I’ll start:
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if they keep switching between soldier and mei only, they clearly have trust issues with supports and need the ability to heal themselves without depending on others
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Sombra or Tracer main make me feel like they actively think it’s their job to be the most annoying shit ever, and often succeed in being frustrating
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Doomfist mains I assume are guys who think it’s cool mastering a niche like him
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mercy mains I automatically assume is a woman (even though I used to main mercy and I’m a man)
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zenyatta mains are either just very good with him or are sick of being asked for heals and swap to him as a “you were being annoying say now I really won’t heal you” nice
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Moira are supports who maybe died to enemy DPS and tanks one too many times and decided to take matters into their own hands now
Etc
If you main hanzo and widow I assume you suffered a lobotomy in your youth