Thats because Sylas ult doesnt literally use the ult, the Devs basically said that if you steal an R as Sylas what would you expect to happen? And being able to actually use the R in the first place is something Id expect. This can be extended to other ults aswell, like Kennen R stunning or Fiora R vitals or Kaisa Passive stacks for R. While Lillia R states that targets need to be affected by her Passive it effectively boils down to the fact the target needs to be hit by a spell within the last 3 (or 4?) Seconds.
I meant it as that youd expect to stun people when you use Kennen R, I just used it as an example of an R that does something when used by Sylas that isnt technically part of the R.